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Port Pirie is the sixth most populous city in South Australia after Adelaide, Mount Gambier, Whyalla, Murray Bridge and Port Lincoln. It is a seaport on the east coast of the Spencer Gulf, 224 km (139 mi) north of Adelaide.
The settlement was founded in 1845 and is the site of the world's largest lead smelter, operated by Nyrstar. It also produces refined silver, zinc, copper and gold.
Prior to European settlement, the location that became Port Pirie was occupied by the indigenous tribe of Nukunu. The location was called 'Tarparrie', which is suspected to mean "Muddy Creek". The first European to see the location was Matthew Flinders in 1802 as he explored the Spencer Gulf by boat. The first land discovery by settlers of the location was by the explorer Edward Eyre who explored regions around Port Augusta. John Horrocks also discovered a pass through the Flinders Ranges to the coast, now named Horrocks Pass.